Steam carrier gas-solid chromatography for high-boiling hydrocarbons
نویسندگان
چکیده
منابع مشابه
Determination of petroleum hydrocarbons in contaminated soils using solid-phase microextraction with gas chromatography-mass spectrometry.
Manual solid-phase microextraction (SPME) coupled with gas chromatography-mass spectrometry is investigated as a possible alternative for the determination of petroleum hydrocarbons in soils. Spiked onto an agricultural soil is a commercial diesel fuel (DF) with the following composition by weight: 12% linear alkanes, 52% saturated hydrocarbons (branched and cyclic), 21% alkylated aromatic hydr...
متن کاملHigh Temperature Gas Chromatography
Gas chromatography (GC) is generally believed to be restricted to the analysis of ‘volatiles’ and is less applicable to the analysis of so-called ‘heavy’ compounds. The introduction of persilylated glass and fused silicea columns, of thermostable stationary phases and of non-discriminative injection devices in capillary GC (CGC) have made the deRnitions of ‘volatile’ and ‘heavy’ very Sexible. H...
متن کاملHyperbolic models in gas-solid chromatography
We present different models arising in chemical engineering and essentially related to isothermal gas chromatography. These models describe a fixed bed adsorption process of separation of a gaseous mixture: each compound can exist either in a mobile phase or a solid and static one, with a finite or infinite mass-exchange kinetics. Many authors, in the fields of chemical engineering and mathemat...
متن کاملQuantitative Analysis of Aromatic Hydrocarbons in Complex Hydrocarbon Mixtures by High Resolution Capillary Gas Chromatography
Natural and synthetic hydrocarbon mixtures are complex samples containing hundreds of different aliphatic and aromatic components in widely differing concentrations. The number of components depends on a group-type composition and the range and distribution of boiling points of the components present in the mixture . Hydrocarbon mixtures are characterised in two ways, by structural group analys...
متن کاملSEPARATION OF POLYCYCLIC AROMATIC HYDROCARBONS WITH MIXED MICELLAR HIGH PERFORMANCE LIQUID CHROMATOGRAPHY
Separation of Polycyclic Aromatic Hydrocarbons was performed by RP-HPLC using mixed micellar mobile phase. Effect of temperature, types and amounts of coorganic solvent in mobile phase on efficiency, asymmetry factor and selectivity factor showed that the appropriate condition for separation of these compounds was 3% isopropanol (V/V) as co-organic solvent in mobile phase at 40°C. Analysis of...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: BUNSEKI KAGAKU
سال: 1971
ISSN: 0525-1931
DOI: 10.2116/bunsekikagaku.20.422